Aqueous Zn2+/Na+ dual-salt batteries with stable discharge voltage and high columbic efficiency by systematic electrolyte regulation

High-Voltage Aqueous Magnesium Ion Batteries

Nonaqueous rechargeable magnesium (Mg) batteries suffer from the complicated and moisture-sensitive electrolyte chemistry. Besides electrolytes, the practicality of a Mg battery is also confined by the absence of high-performance electrode materials due to the intrinsically slow Mg2+ diffusion in the solids. In this work, we demonstrated a rechargeable aqueous magnesium ion battery (AMIB) conce...

"Water-in-salt" electrolyte enables high-voltage aqueous lithium-ion chemistries.

Lithium-ion batteries raise safety, environmental, and cost concerns, which mostly arise from their nonaqueous electrolytes. The use of aqueous alternatives is limited by their narrow electrochemical stability window (1.23 volts), which sets an intrinsic limit on the practical voltage and energy output. We report a highly concentrated aqueous electrolyte whose window was expanded to ~3.0 volts ...

Electrolyte limitation of fast discharge in lithium batteries and supercapacitors

Voltage increase of aqueous lithium-ion batteries by Li-ion conducting Li1.5Al0.5Ge1.5(PO4)3 glass-ceramic

  In this research, a lithium ion conducting lithium aluminum germanium phosphate (LAGP) glass-ceramic with a formula of Li1.5Al0.5Ge1.5(PO4)3 was synthesized by melt-quenching method and subsequent crystallization at 850 °C for 8 h. The prepared glass-ceramic was characterized using X-ray diffraction analysis (XRD) and field emission scanning electron microscopy (FESEM). The XRD patterns exhib...

High-Columbic-Efficiency Lithium Battery Based on Silicon Particle Materials

Micro-sized polycrystalline silicon particles were used as anode materials of lithium-ion battery. The columbic efficiency of the first cycle reached a relatively high value of 91.8 % after prelithiation and increased to 99 % in the second cycle. Furthermore, columbic efficiency remained above 99 % for up to 280+ cycles. The excellent performances of the batteries were the results of the use of...